B.Sc. (General) 4th Semester
Physics
Paper: A Statistical Physics and Thermodynamic-II
Time Allowed: Three Hours
Maximum Marks: 22
Note: - (1) Attempt five questions in all, selecting two each from
Unit I and II. Unit III is compulsory
(2) All questions carry marks as indicated.
(3) Non-Programmable Calculators are allowed.
(4) Logarithmic Tables can be asked.
UNIT-I
I. (a) Find the relation for the entropy of one mole of an ideal gas.
2 (b) Find the change in entropy of one mole of carbon dioxide when its absolute temperature increased by 3 times if the process of heating is :
(i) Isochoric
(ii) Isobaric
II. (a) Define and find expressions for Thermo-emf, Peltier co-efficient, and Thomson co-efficient.
(b) The entropy of v= 3.0 moles of an ideal gas increases, by S = 23 JK-1 due to isothermal expansion. How many times should the volume of the gas be increased or decreased ?
III. (a) How does a Heat pump differ from Refrigerator? Prove that the amount of mechanical energy required to extract a given amount of heat from a cold body increases with a decrease in temperature of the body, for a given temperature of the sink.
(b) A heat engine employing a Carnot cycle with an efficiency of n = 20% is used as a refrigerating machine, the thermal reservoir being the same. Find its refrigerating efficiency €.
UNIT-II
IV. (a) Derive Clapeyron's equation from Maxwell's relations and explain the change of ice to water on the basis of it.
(b) Making use of Maxwell's thermodynamical relation prove that cooling is produced when the substance which contracts on heating is compressed.
V. (a) What are thermodynamic potentials? What is their significance? Deduce the relation
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